Synthesis, spectroscopic characterization and thermogravimetric analysis of two series of substituted (metallo)tetraphenylporphyrins

Subsequent treatment of H(2)TPP(CO(2)H)(4) (tetra(p-carboxylic acid phenyl)porphyrin, 1) with an excess of oxalyl chloride and HNR(2) afforded H(2)TPP(C(O)NR(2))(4) (R = Me, 2; iPr, 3) with yields exceeding 80%. The porphyrins 2 and 3 could be converted to the corresponding metalloporphyrins MTPP(C(...

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Detalles Bibliográficos
Autores principales: Al-Shewiki, Rasha K, Mende, Carola, Buschbeck, Roy, Siles, Pablo F, Schmidt, Oliver G, Rüffer, Tobias, Lang, Heinrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5480337/
https://www.ncbi.nlm.nih.gov/pubmed/28685120
http://dx.doi.org/10.3762/bjnano.8.121

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5480337/
https://www.ncbi.nlm.nih.gov/pubmed/28685120
http://dx.doi.org/10.3762/bjnano.8.121

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