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Urea–hydrogen peroxide prompted the selective and controlled oxidation of thioglycosides into sulfoxides and sulfones

A practical method for the selective and controlled oxidation of thioglycosides to corresponding glycosyl sulfoxides and sulfones is reported using urea–hydrogen peroxide (UHP). A wide range of glycosyl sulfoxides are selectively achieved using 1.5 equiv of UHP at 60 °C while corresponding sulfones...

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Detalles Bibliográficos
Autores principales: Singh, Adesh Kumar, Tiwari, Varsha, Mishra, Kunj Bihari, Gupta, Surabhi, Kandasamy, Jeyakumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5480342/
https://www.ncbi.nlm.nih.gov/pubmed/28684993
http://dx.doi.org/10.3762/bjoc.13.113