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Transition-metal-free one-pot synthesis of alkynyl selenides from terminal alkynes under aerobic and sustainable conditions

Alkynyl selenides were synthesized by a straightforward one-pot and three-step methodology, without the need of diselenides as starting reagents, under an oxygen atmosphere and using PEG 200 as the solvent. This procedure involves the in situ generation of dialkyl diselenides through a K(3)PO(4)-ass...

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Detalles Bibliográficos
Autores principales: Heredia, Adrián A, Peñéñory, Alicia B
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5480365/
https://www.ncbi.nlm.nih.gov/pubmed/28684972
http://dx.doi.org/10.3762/bjoc.13.92