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Stereocontrolled Total Synthesis of (−)‐Stemaphylline
Homologation of readily available α‐boryl pyrrolidines with metal carbenoids is especially challenging even when good leaving groups (Cl(−)) are employed. By performing a solvent switch from Et(2)O to CHCl(3), efficient 1,2‐metalate rearrangement of the intermediate boronate occurs with both halide...
Autores principales: | Varela, Ana, Garve, Lennart K. B., Leonori, Daniele, Aggarwal, Varinder K. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5484348/ https://www.ncbi.nlm.nih.gov/pubmed/28097799 http://dx.doi.org/10.1002/anie.201611273 |
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