Palladium‐Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals

Palladium(II) in combination with a monodentate phosphine ligand enables the unprecedented direct and α‐stereoselective catalytic synthesis of deoxyglycosides from glycals. Initial mechanistic studies suggest that in the presence of N‐phenyl‐2‐(di‐tert‐butylphosphino)pyrrole as the ligand, the react...

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Detalles Bibliográficos
Autores principales: Sau, Abhijit, Williams, Ryan, Palo‐Nieto, Carlos, Franconetti, Antonio, Medina, Sandra, Galan, M. Carmen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5484376/
https://www.ncbi.nlm.nih.gov/pubmed/28211228
http://dx.doi.org/10.1002/anie.201612071

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5484376/
https://www.ncbi.nlm.nih.gov/pubmed/28211228
http://dx.doi.org/10.1002/anie.201612071

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