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Successive light-induced two electron transfers in a Ru–Fe supramolecular assembly: from Ru–Fe(ii)–OH(2) to Ru–Fe(iv)–oxo
In the present work we describe the synthesis and study of a Ru(II)–Fe(II) chromophore–catalyst assembly designed to perform the light-induced activation of an iron bound water molecule and subsequent photo-driven oxidation of a substrate. Using a series of spectroscopic techniques, we demonstrate t...
Autores principales: | , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5488195/ https://www.ncbi.nlm.nih.gov/pubmed/28706653 http://dx.doi.org/10.1039/c5sc00024f |