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Unexpected effect of catalyst concentration on photochemical CO(2) reduction by trans(Cl)–Ru(bpy)(CO)(2)Cl(2): new mechanistic insight into the CO/HCOO(–) selectivity
Photochemical CO(2) reduction catalysed by trans(Cl)–Ru(bpy)(CO)(2)Cl(2) (bpy = 2,2′-bipyridine) efficiently produces carbon monoxide (CO) and formate (HCOO(–)) in N,N-dimethylacetamide (DMA)/water containing [Ru(bpy)(3)](2+) as a photosensitizer and 1-benzyl-1,4-dihydronicotinamide (BNAH) as an ele...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5490049/ https://www.ncbi.nlm.nih.gov/pubmed/28706681 http://dx.doi.org/10.1039/c5sc00199d |