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Unexpected effect of catalyst concentration on photochemical CO(2) reduction by trans(Cl)–Ru(bpy)(CO)(2)Cl(2): new mechanistic insight into the CO/HCOO(–) selectivity

Photochemical CO(2) reduction catalysed by trans(Cl)–Ru(bpy)(CO)(2)Cl(2) (bpy = 2,2′-bipyridine) efficiently produces carbon monoxide (CO) and formate (HCOO(–)) in N,N-dimethylacetamide (DMA)/water containing [Ru(bpy)(3)](2+) as a photosensitizer and 1-benzyl-1,4-dihydronicotinamide (BNAH) as an ele...

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Detalles Bibliográficos
Autores principales:	Kuramochi, Yusuke, Itabashi, Jun, Fukaya, Kyohei, Enomoto, Akito, Yoshida, Makoto, Ishida, Hitoshi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2015
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5490049/ https://www.ncbi.nlm.nih.gov/pubmed/28706681 http://dx.doi.org/10.1039/c5sc00199d

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