A high-spin square-planar Fe(ii) complex stabilized by a trianionic pincer-type ligand and conclusive evidence for retention of geometry and spin state in solution

Square-planar high-spin Fe(ii) molecular compounds are rare and the only three non-macrocyclic or sterically-driven examples reported share a common FeO(4) core. Using an easily modifiable pincer-type ligand, the successful synthesis of the first compound of this type that breaks the FeO(4) motif wa...

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Detalles Bibliográficos
Autores principales: Pascualini, M. E., Di Russo, N. V., Thuijs, A. E., Ozarowski, A., Stoian, S. A., Abboud, K. A., Christou, G., Veige, A. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5491960/
https://www.ncbi.nlm.nih.gov/pubmed/28706628
http://dx.doi.org/10.1039/c4sc02634a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5491960/
https://www.ncbi.nlm.nih.gov/pubmed/28706628
http://dx.doi.org/10.1039/c4sc02634a

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