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A high-spin square-planar Fe(ii) complex stabilized by a trianionic pincer-type ligand and conclusive evidence for retention of geometry and spin state in solution
Square-planar high-spin Fe(ii) molecular compounds are rare and the only three non-macrocyclic or sterically-driven examples reported share a common FeO(4) core. Using an easily modifiable pincer-type ligand, the successful synthesis of the first compound of this type that breaks the FeO(4) motif wa...
Autores principales: | Pascualini, M. E., Di Russo, N. V., Thuijs, A. E., Ozarowski, A., Stoian, S. A., Abboud, K. A., Christou, G., Veige, A. S. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5491960/ https://www.ncbi.nlm.nih.gov/pubmed/28706628 http://dx.doi.org/10.1039/c4sc02634a |
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