Generation of 1,2-azaboretidines via reduction of ADC borane adducts

Reaction of the acyclic (diamino)carbene (ADC) :C(NiPr(2))(2) (1) with different dihaloboranes of the type RBX(2) (R = Mes, Dur; X = Cl, Br) smoothly afforded a novel class of ADC-stabilized borane adducts. For MesBBr(2) however, the reaction did not stop at the adduct level, but an uncommon rearran...

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Detalles Bibliográficos
Autores principales: Braunschweig, H., Gackstatter, A., Kupfer, T., Scheller, T., Hupp, F., Damme, A., Arnold, N., Ewing, W. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492900/
https://www.ncbi.nlm.nih.gov/pubmed/28706706
http://dx.doi.org/10.1039/c5sc01077b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492900/
https://www.ncbi.nlm.nih.gov/pubmed/28706706
http://dx.doi.org/10.1039/c5sc01077b

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