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Generation of 1,2-azaboretidines via reduction of ADC borane adducts
Reaction of the acyclic (diamino)carbene (ADC) :C(NiPr(2))(2) (1) with different dihaloboranes of the type RBX(2) (R = Mes, Dur; X = Cl, Br) smoothly afforded a novel class of ADC-stabilized borane adducts. For MesBBr(2) however, the reaction did not stop at the adduct level, but an uncommon rearran...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5492900/ https://www.ncbi.nlm.nih.gov/pubmed/28706706 http://dx.doi.org/10.1039/c5sc01077b |