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Chiral tether-mediated stabilization and helix-sense control of complementary metallo-double helices

A series of novel Pt(II)-linked double helices were prepared by inter- or intrastrand ligand-exchange reactions of the complementary duplexes composed of chiral or achiral amidine dimer and achiral carboxylic acid dimer strands joined by trans-Pt(II)–acetylide complexes with PPh(3) ligands using chi...

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Detalles Bibliográficos
Autores principales: Horie, Miki, Ousaka, Naoki, Taura, Daisuke, Yashima, Eiji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5494540/
https://www.ncbi.nlm.nih.gov/pubmed/28706634
http://dx.doi.org/10.1039/c4sc02275k