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Formation of a C–C double bond from two aliphatic carbons. Multiple C–H activations in an iridium pincer complex

The search for novel, atom-economic methods for the formation of C–C bonds is of crucial importance in synthetic chemistry. Especially attractive are reactions where C–C bonds are formed through C–H activation, but the coupling of unactivated, alkane-type C(sp(3) )–H bonds remains an unsolved challe...

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Detalles Bibliográficos
Autores principales: Polukeev, Alexey V., Marcos, Rocío, Ahlquist, Mårten S. G., Wendt, Ola F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5496475/
https://www.ncbi.nlm.nih.gov/pubmed/28717458
http://dx.doi.org/10.1039/c4sc03839h