Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines

Stepwise oxidation of 1,8-bis(diphenylphosphino)naphthalene and a series of (oligo)methylene-linked diphosphines with XeF(2) followed by fluoride abstraction yields a family of compounds featuring phosphine, phosphonium and phosphorane moieties in close proximity. The bisphosphonium ions [(C(10)H(6)...

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Detalles Bibliográficos
Autores principales: Holthausen, Michael H., Hiranandani, Rashi R., Stephan, Douglas W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5496503/
https://www.ncbi.nlm.nih.gov/pubmed/28717457
http://dx.doi.org/10.1039/c5sc00051c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5496503/
https://www.ncbi.nlm.nih.gov/pubmed/28717457
http://dx.doi.org/10.1039/c5sc00051c

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