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Dramatic band gap reduction incurred by dopant coordination rearrangement in Co-doped nanocrystals of CeO(2)

A dramatic band gap narrowing of 1.61 eV has been observed in Co-doped nanocrystals of CeO(2) (ceria), as a result of thermal annealing, without changing the ceria crystal structure and the Co concentration. As demonstrated by x-ray absorption fine structures, thermal annealing incurs an oxygen coor...

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Detalles Bibliográficos
Autores principales: Wu, T. S., Chen, Y. W., Weng, S. C., Lin, C. N., Lai, C. H., Huang, Y. J., Jeng, H. T., Chang, S. L., Soo, Y. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5498595/
https://www.ncbi.nlm.nih.gov/pubmed/28680089
http://dx.doi.org/10.1038/s41598-017-05046-0