Palladium carbene complexes as persistent radicals

A series of palladium(ii) radical carbene complexes, [PC˙(sp(2))P]PdI, [PC˙(sp(2))P]PdBr, and [PC˙(sp(2))P]PdCl (PC(sp(3))H(2)P = bis[2-(di-iso-propylphosphino)-phenyl]methane), is described. Compound [PC˙(sp(2))P]PdI dimerizes to {[PC(sp(2))P]PdI}(2) in the solid state, akin to the formation of Gom...

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Detalles Bibliográficos
Autores principales: Comanescu, C. C., Vyushkova, M., Iluc, V. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5500858/
https://www.ncbi.nlm.nih.gov/pubmed/28717474
http://dx.doi.org/10.1039/c5sc01441g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5500858/
https://www.ncbi.nlm.nih.gov/pubmed/28717474
http://dx.doi.org/10.1039/c5sc01441g

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