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Palladium carbene complexes as persistent radicals
A series of palladium(ii) radical carbene complexes, [PC˙(sp(2))P]PdI, [PC˙(sp(2))P]PdBr, and [PC˙(sp(2))P]PdCl (PC(sp(3))H(2)P = bis[2-(di-iso-propylphosphino)-phenyl]methane), is described. Compound [PC˙(sp(2))P]PdI dimerizes to {[PC(sp(2))P]PdI}(2) in the solid state, akin to the formation of Gom...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5500858/ https://www.ncbi.nlm.nih.gov/pubmed/28717474 http://dx.doi.org/10.1039/c5sc01441g |