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Well-defined silica supported aluminum hydride: another step towards the utopian single site dream?

Reaction of triisobutylaluminum with SBA15(700) at room temperature occurs by two parallel pathways involving either silanol or siloxane bridges. It leads to the formation of a well-defined bipodal [([triple bond, length as m-dash]SiO)(2)Al–CH(2)CH(CH(3))(2)] 1a, silicon isobutyl [[triple bond, leng...

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Detalles Bibliográficos
Autores principales: Werghi, Baraa, Bendjeriou-Sedjerari, Anissa, Sofack-Kreutzer, Julien, Jedidi, Abdesslem, Abou-Hamad, Edy, Cavallo, Luigi, Basset, Jean-Marie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5505125/
https://www.ncbi.nlm.nih.gov/pubmed/28757945
http://dx.doi.org/10.1039/c5sc02276b