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Well-defined silica supported aluminum hydride: another step towards the utopian single site dream?
Reaction of triisobutylaluminum with SBA15(700) at room temperature occurs by two parallel pathways involving either silanol or siloxane bridges. It leads to the formation of a well-defined bipodal [([triple bond, length as m-dash]SiO)(2)Al–CH(2)CH(CH(3))(2)] 1a, silicon isobutyl [[triple bond, leng...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5505125/ https://www.ncbi.nlm.nih.gov/pubmed/28757945 http://dx.doi.org/10.1039/c5sc02276b |