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Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni(ii)

Monometallic complexes based on 3d transition metal ions in certain axial coordination environments can exhibit appreciably enhanced magnetic anisotropy, important for memory applications, due to stabilisation of an unquenched orbital moment. For high-spin trigonal bipyramidal Ni(ii), if competing s...

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Detalles Bibliográficos
Autores principales: Marriott, Katie E. R., Bhaskaran, Lakshmi, Wilson, Claire, Medarde, Marisa, Ochsenbein, Stefan T., Hill, Stephen, Murrie, Mark
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5508675/
https://www.ncbi.nlm.nih.gov/pubmed/28757973
http://dx.doi.org/10.1039/c5sc02854j