Pushing NMR sensitivity limits using dynamic nuclear polarization with closed-loop cryogenic helium sample spinning

We report a strategy to push the limits of solid-state NMR sensitivity far beyond its current state-of-the-art. The approach relies on the use of dynamic nuclear polarization and demonstrates unprecedented DNP enhancement factors for experiments performed at sample temperatures much lower than 100 K...

Descripción completa

Detalles Bibliográficos
Autores principales: Bouleau, E., Saint-Bonnet, P., Mentink-Vigier, F., Takahashi, H., Jacquot, J.-F., Bardet, M., Aussenac, F., Purea, A., Engelke, F., Hediger, S., Lee, D., De Paëpe, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5508678/
https://www.ncbi.nlm.nih.gov/pubmed/28757972
http://dx.doi.org/10.1039/c5sc02819a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5508678/
https://www.ncbi.nlm.nih.gov/pubmed/28757972
http://dx.doi.org/10.1039/c5sc02819a

Ejemplares similares