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Coordination of {Mo(142)} Ring to La(3+) Provides Elliptical {Mo(134)La(10)} Ring with a Variety of Coordination Modes

A 28-electron reduced C(2h)-Mo-blue 34Ǻ outer ring diameter circular ring, [Mo(142)O(429)H(10)(H(2)O)(49)(CH(3)CO(2))(5)(C(2)H(5)CO(2))](30-) (≡{Mo(142)(CH(3)CO(2))(5)(C(2)H(5)CO(2))}) comprising eight carboxylate-coordinated (with disorder) {Mo(2)} linkers and six defect pockets in two inner rings...

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Detalles Bibliográficos
Autores principales: Ishikawa, Eri, Yano, Yutaka, Yamase, Toshihiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5510172/
http://dx.doi.org/10.3390/ma3010064