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Coordination of {Mo(142)} Ring to La(3+) Provides Elliptical {Mo(134)La(10)} Ring with a Variety of Coordination Modes
A 28-electron reduced C(2h)-Mo-blue 34Ǻ outer ring diameter circular ring, [Mo(142)O(429)H(10)(H(2)O)(49)(CH(3)CO(2))(5)(C(2)H(5)CO(2))](30-) (≡{Mo(142)(CH(3)CO(2))(5)(C(2)H(5)CO(2))}) comprising eight carboxylate-coordinated (with disorder) {Mo(2)} linkers and six defect pockets in two inner rings...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Molecular Diversity Preservation International
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5510172/ http://dx.doi.org/10.3390/ma3010064 |