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Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine

A mononuclear complex [MoOCl(4)(H(2)O)](−) readily forms a metal−metal bonded {Mo(2)O(4)}(2+) core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo(2)O(4)Cl(2)(Py)(4)] composition is...

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Detalles Bibliográficos
Autores principales: Modec, Barbara, Zubieta, Jon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5510186/
http://dx.doi.org/10.3390/ma3010150