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Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine
A mononuclear complex [MoOCl(4)(H(2)O)](−) readily forms a metal−metal bonded {Mo(2)O(4)}(2+) core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo(2)O(4)Cl(2)(Py)(4)] composition is...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Molecular Diversity Preservation International
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5510186/ http://dx.doi.org/10.3390/ma3010150 |
| Sumario: | A mononuclear complex [MoOCl(4)(H(2)O)](−) readily forms a metal−metal bonded {Mo(2)O(4)}(2+) core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo(2)O(4)Cl(2)(Py)(4)] composition is isolated as a product. Solid state structures of two compounds containing this complex, [Mo(2)O(4)Cl(2)(Py)(4)]·2.25Py (1) and [Mo(2)O(4)Cl(2)(Py)(4)]·1.5PyHCl (2), were investigated by X-ray crystallography. |
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