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Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine
A mononuclear complex [MoOCl(4)(H(2)O)](−) readily forms a metal−metal bonded {Mo(2)O(4)}(2+) core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo(2)O(4)Cl(2)(Py)(4)] composition is...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Molecular Diversity Preservation International
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5510186/ http://dx.doi.org/10.3390/ma3010150 |
| _version_ | 1783250137014861824 |
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| author | Modec, Barbara Zubieta, Jon |
| author_facet | Modec, Barbara Zubieta, Jon |
| author_sort | Modec, Barbara |
| collection | PubMed |
| description | A mononuclear complex [MoOCl(4)(H(2)O)](−) readily forms a metal−metal bonded {Mo(2)O(4)}(2+) core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo(2)O(4)Cl(2)(Py)(4)] composition is isolated as a product. Solid state structures of two compounds containing this complex, [Mo(2)O(4)Cl(2)(Py)(4)]·2.25Py (1) and [Mo(2)O(4)Cl(2)(Py)(4)]·1.5PyHCl (2), were investigated by X-ray crystallography. |
| format | Online Article Text |
| id | pubmed-5510186 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | Molecular Diversity Preservation International |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-55101862017-07-28 Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine Modec, Barbara Zubieta, Jon Materials (Basel) Article A mononuclear complex [MoOCl(4)(H(2)O)](−) readily forms a metal−metal bonded {Mo(2)O(4)}(2+) core. A high content of pyridine in the reaction mixture prevents further aggregation of dinuclear cores into larger clusters and a neutral, dinuclear complex with the [Mo(2)O(4)Cl(2)(Py)(4)] composition is isolated as a product. Solid state structures of two compounds containing this complex, [Mo(2)O(4)Cl(2)(Py)(4)]·2.25Py (1) and [Mo(2)O(4)Cl(2)(Py)(4)]·1.5PyHCl (2), were investigated by X-ray crystallography. Molecular Diversity Preservation International 2010-01-04 /pmc/articles/PMC5510186/ http://dx.doi.org/10.3390/ma3010150 Text en © 2010 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). |
| spellingShingle | Article Modec, Barbara Zubieta, Jon Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine |
| title | Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine |
| title_full | Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine |
| title_fullStr | Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine |
| title_full_unstemmed | Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine |
| title_short | Syntheses and a Solid State Structure of a Dinuclear Molybdenum(V) Complex with Pyridine |
| title_sort | syntheses and a solid state structure of a dinuclear molybdenum(v) complex with pyridine |
| topic | Article |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5510186/ http://dx.doi.org/10.3390/ma3010150 |
| work_keys_str_mv | AT modecbarbara synthesesandasolidstatestructureofadinuclearmolybdenumvcomplexwithpyridine AT zubietajon synthesesandasolidstatestructureofadinuclearmolybdenumvcomplexwithpyridine |