Cargando…

Chemoselectivity in the Dehydrocoupling Synthesis of Higher Molecular Weight Polysilanes

The Cp(2)ZrCl(2)/2 BuLi catalyzed co-polymerization of H(2)MeSiSiMeH(2) and PhSiH(3) was compared to the homo-polymerization of H(2)MeSiSiPhH(2). In contrast to the co-polymerization, which gave molecular weights comparable to homo-polymerization of phenylsilane, the reaction of 1-methyl-2-phenyldis...

Descripción completa

Detalles Bibliográficos
Autores principales: Lunzer, Florian, Marschner, Christoph
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5513459/
http://dx.doi.org/10.3390/ma3021125