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Chemoselectivity in the Dehydrocoupling Synthesis of Higher Molecular Weight Polysilanes
The Cp(2)ZrCl(2)/2 BuLi catalyzed co-polymerization of H(2)MeSiSiMeH(2) and PhSiH(3) was compared to the homo-polymerization of H(2)MeSiSiPhH(2). In contrast to the co-polymerization, which gave molecular weights comparable to homo-polymerization of phenylsilane, the reaction of 1-methyl-2-phenyldis...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Molecular Diversity Preservation International
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5513459/ http://dx.doi.org/10.3390/ma3021125 |