Persistent four-coordinate iron-centered radical stabilized by π-donation

Dinuclear iron carbonyl complex 2, which contains an elongated unsupported Fe–Fe bond, was synthesized by the reaction between Fe(2)(CO)(9) and phosphinyl radical 1. Thermal Fe–Fe bond homolysis led to the generation of a four-coordinate carbonyl-based iron-centered radical, 3, which is stabilized b...

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Detalles Bibliográficos
Autores principales: Sunada, Yusuke, Ishida, Shintaro, Hirakawa, Fumiya, Shiota, Yoshihito, Yoshizawa, Kazunari, Kanegawa, Shinji, Sato, Osamu, Nagashima, Hideo, Iwamoto, Takeaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5515065/
https://www.ncbi.nlm.nih.gov/pubmed/28758000
http://dx.doi.org/10.1039/c5sc02601f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5515065/
https://www.ncbi.nlm.nih.gov/pubmed/28758000
http://dx.doi.org/10.1039/c5sc02601f

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