Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes

[Image: see text] We report the first enantioselective Rh-catalyzed Markovnikov hydroboration of unactivated terminal alkenes. Using a novel sp(2)–sp(3) hybridized diboron reagent and water as a proton source, a broad range of alkenes undergo hydroboration to provide secondary boronic esters with hi...

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Detalles Bibliográficos
Autores principales: Smith, James R., Collins, Beatrice S. L., Hesse, Matthew J., Graham, Mark A., Myers, Eddie L., Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5515510/
https://www.ncbi.nlm.nih.gov/pubmed/28665124
http://dx.doi.org/10.1021/jacs.7b05149

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5515510/
https://www.ncbi.nlm.nih.gov/pubmed/28665124
http://dx.doi.org/10.1021/jacs.7b05149

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