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Iron L(2,3)-Edge X-ray Absorption and X-ray Magnetic Circular Dichroism Studies of Molecular Iron Complexes with Relevance to the FeMoco and FeVco Active Sites of Nitrogenase

[Image: see text] Herein, a systematic study of a series of molecular iron model complexes has been carried out using Fe L(2,3)-edge X-ray absorption (XAS) and X-ray magnetic circular dichroism (XMCD) spectroscopies. This series spans iron complexes of increasing complexity, starting from ferric and...

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Detalles Bibliográficos
Autores principales: Kowalska, Joanna K., Nayyar, Brahamjot, Rees, Julian A., Schiewer, Christine E., Lee, Sonny C., Kovacs, Julie A., Meyer, Franc, Weyhermüller, Thomas, Otero, Edwige, DeBeer, Serena
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5516708/
https://www.ncbi.nlm.nih.gov/pubmed/28653855
http://dx.doi.org/10.1021/acs.inorgchem.7b00852