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Pd-η (3)-C(6)H(9) complexes of the Trost modular ligand: high nuclearity columnar aggregation controlled by concentration, solvent and counterion

Under optimised conditions, the Trost modular ligand (TML) series induces high levels of asymmetric induction in an extraordinarily wide range of reactions involving palladium π-allyl intermediates. Prior mechanistic investigations into reactions involving Pd-η (3)-C(6)H(9) intermediates have focuss...

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Detalles Bibliográficos
Autores principales: Racys, Daugirdas Tomas, Eastoe, Julian, Norrby, Per-Ola, Grillo, Isabelle, Rogers, Sarah E., Lloyd-Jones, Guy C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5520773/
https://www.ncbi.nlm.nih.gov/pubmed/28791087
http://dx.doi.org/10.1039/c5sc01181g