Activation of Dinitrogen as A Dipolarophile in 1,3-Dipolar Cycloadditions: A Theoretical Study Using Nitrile Imines as “Octet” 1,3-Dipoles

Theoretical calculations at the G4MP2 level of theory demonstrate that it is possible to activate dinitrogen to make it react in dipolar cycloadditions using neutral beryllium derivatives and other neutral metallic compounds. For the particular case of beryllium, the barrier decreases more than 40 k...

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Detalles Bibliográficos
Autores principales: Montero-Campillo, M. Merced, Alkorta, Ibon, Elguero, José
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5522451/
https://www.ncbi.nlm.nih.gov/pubmed/28733626
http://dx.doi.org/10.1038/s41598-017-05708-z

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5522451/
https://www.ncbi.nlm.nih.gov/pubmed/28733626
http://dx.doi.org/10.1038/s41598-017-05708-z

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