Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles

The electron-deficient pentaarylborole 1-(2′,4′,6′-tris(trifluoromethyl)phenyl)-2,3,4,5-tetraphenylborole (1) has been synthesised with the long-term aim of developing borole-based optoelectronic materials. The bulky 2,4,6-tris(trifluoromethyl)phenyl (FMes) group on the boron atom of 1 significantly...

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Detalles Bibliográficos
Autores principales: Zhang, Zuolun, Edkins, Robert M., Haehnel, Martin, Wehner, Marius, Eichhorn, Antonius, Mailänder, Lisa, Meier, Michael, Brand, Johannes, Brede, Franziska, Müller-Buschbaum, Klaus, Braunschweig, Holger, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5523080/
https://www.ncbi.nlm.nih.gov/pubmed/28791091
http://dx.doi.org/10.1039/c5sc02205c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5523080/
https://www.ncbi.nlm.nih.gov/pubmed/28791091
http://dx.doi.org/10.1039/c5sc02205c

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