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Synthesis, structure, and reactions of a copper–sulfido cluster comprised of the parent Cu(2)S unit: {(NHC)Cu}(2)(μ-S)
The synthesis of the first CuI2(μ-S) complex, {(IPr*)Cu}(2)(μ-S) (IPr* = 1,3-bis(2,6-(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene; 1), has been accomplished via three synthetic routes: (1) salt metathesis between (IPr*)CuCl and Na(2)S; (2) silyl-deprotection reaction between (IPr*)Cu(SSiMe(3))...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5523119/ https://www.ncbi.nlm.nih.gov/pubmed/28791108 http://dx.doi.org/10.1039/c5sc03258j |