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High symmetry or low symmetry, that is the question – high performance Dy(iii) single-ion magnets by electrostatic potential design

A series of mononuclear lanthanide Zn–Dy–Zn type single-molecule magnets (SMMs) were synthesized and magnetically characterized. The four molecules ([Zn(2)(L(1))(2)DyCl(3)]·2H(2)O (1), [Zn(2)(L(1))(2)Dy(MeOH)Br(3)]·3H(2)O (2), [Zn(2)(L(1))(2)Dy(H(2)O)Br(2)]·[ZnBr(4)](0.5) (3) and [Zn(2)(L(2))(2)DyCl...

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Detalles Bibliográficos
Autores principales: Sun, Wen-Bin, Yan, Peng-Fei, Jiang, Shang-Da, Wang, Bing-Wu, Zhang, Yi-Quan, Li, Hong-Feng, Chen, Peng, Wang, Zhe-Ming, Gao, Song
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5523121/
https://www.ncbi.nlm.nih.gov/pubmed/28791111
http://dx.doi.org/10.1039/c5sc02986d