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Transition-Metal Catalysis of Nucleophilic Substitution Reactions: A Radical Alternative to S(N)1 and S(N)2 Processes
[Image: see text] Classical methods for achieving nucleophilic substitutions of alkyl electrophiles (S(N)1 and S(N)2) have limited scope and are not generally amenable to enantioselective variants that employ readily available racemic electrophiles. Radical-based pathways catalyzed by chiral transit...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5532721/ https://www.ncbi.nlm.nih.gov/pubmed/28776010 http://dx.doi.org/10.1021/acscentsci.7b00212 |