Subcomponent Exchange Transforms an Fe(II)(4)L(4) Cage from High- to Low-Spin, Switching Guest Release in a Two-Cage System

[Image: see text] Subcomponent exchange transformed new high-spin Fe(II)(4)L(4) cage 1 into previously-reported low-spin Fe(II)(4)L(4) cage 2: 2-formyl-6-methylpyridine was ejected in favor of the less sterically hindered 2-formylpyridine, with concomitant high- to low-spin transition of the cage’s...

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Detalles Bibliográficos
Autores principales: McConnell, Anna J., Aitchison, Catherine M., Grommet, Angela B., Nitschke, Jonathan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5537689/
https://www.ncbi.nlm.nih.gov/pubmed/28426930
http://dx.doi.org/10.1021/jacs.7b01478

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5537689/
https://www.ncbi.nlm.nih.gov/pubmed/28426930
http://dx.doi.org/10.1021/jacs.7b01478

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