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Subcomponent Exchange Transforms an Fe(II)(4)L(4) Cage from High- to Low-Spin, Switching Guest Release in a Two-Cage System
[Image: see text] Subcomponent exchange transformed new high-spin Fe(II)(4)L(4) cage 1 into previously-reported low-spin Fe(II)(4)L(4) cage 2: 2-formyl-6-methylpyridine was ejected in favor of the less sterically hindered 2-formylpyridine, with concomitant high- to low-spin transition of the cage’s...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5537689/ https://www.ncbi.nlm.nih.gov/pubmed/28426930 http://dx.doi.org/10.1021/jacs.7b01478 |