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Mild Reductive Functionalization of Amides into N‐Sulfonylformamidines

The development of a protocol for the reductive functionalization of amides into N‐sulfonylformamidines is reported. The one‐pot procedure is based on a mild catalytic reduction of tertiary amides into the corresponding enamines by the use of Mo(CO)(6) (molybdenum hexacarbonyl) and TMDS (1,1,3,3‐tet...

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Detalles Bibliográficos
Autores principales: Trillo, Paz, Slagbrand, Tove, Tinnis, Fredrik, Adolfsson, Hans
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5542752/
https://www.ncbi.nlm.nih.gov/pubmed/28794940
http://dx.doi.org/10.1002/open.201700087