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Electronic Delocalization in the Radical Cations of Porphyrin Oligomer Molecular Wires

[Image: see text] The radical cations of a family of π-conjugated porphyrin arrays have been investigated: linear chains of N = 1–6 porphyrins, a 6-porphyrin nanoring and a 12-porphyrin nanotube. The radical cations were generated in solution by chemical and electrochemical oxidation, and probed by...

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Detalles Bibliográficos
Autores principales: Peeks, Martin D., Tait, Claudia E., Neuhaus, Patrik, Fischer, Georg M., Hoffmann, Markus, Haver, Renée, Cnossen, Arjen, Harmer, Jeffrey R., Timmel, Christiane R., Anderson, Harry L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5543395/
https://www.ncbi.nlm.nih.gov/pubmed/28678489
http://dx.doi.org/10.1021/jacs.7b05386