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Electronic Delocalization in the Radical Cations of Porphyrin Oligomer Molecular Wires
[Image: see text] The radical cations of a family of π-conjugated porphyrin arrays have been investigated: linear chains of N = 1–6 porphyrins, a 6-porphyrin nanoring and a 12-porphyrin nanotube. The radical cations were generated in solution by chemical and electrochemical oxidation, and probed by...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5543395/ https://www.ncbi.nlm.nih.gov/pubmed/28678489 http://dx.doi.org/10.1021/jacs.7b05386 |