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Deracemization of a Racemic Allylic Sulfoxide Using Viedma Ripening

[Image: see text] Despite the importance of enantiopure chiral sulfoxides, few methods exist that allow for their deracemization. Here, we show that an enantiopure sulfoxide can be produced from the corresponding racemate using Viedma ripening involving rearrangement-induced racemization. The suitab...

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Detalles Bibliográficos
Autores principales: Engwerda, Anthonius H. J., Koning, Niels, Tinnemans, Paul, Meekes, Hugo, Bickelhaupt, F. Matthias, Rutjes, Floris P. J. T., Vlieg, Elias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5543398/
https://www.ncbi.nlm.nih.gov/pubmed/28794692
http://dx.doi.org/10.1021/acs.cgd.7b00828