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Phenylsilane as an effective desulfinylation reagent

The reduction using phenylsilane in a KOH-catalyzed system was applied successfully to the conversion of sulfinyl-substituted cyclopropylcarboxylates into the corresponding alcohols. The presence of sulfinyl substituents in the α-position to the carboxylate group caused a desulfinylation product for...

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Detalles Bibliográficos
Autores principales: Midura, Wanda H, Rzewnicka, Aneta, Krysiak, Jerzy A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5550773/
https://www.ncbi.nlm.nih.gov/pubmed/28845195
http://dx.doi.org/10.3762/bjoc.13.150