Tuning the Stability of Pd(IV) Intermediates Using a Redox Non-innocent Ligand Combined with an Organolanthanide Fragment

[Image: see text] The unique combination of a divalent organolanthanide fragment, Cp*(2)Yb, with bipyrimidine (bipym) and a palladium bis-alkyl fragment, PdMe(2), allows the rapid formation and stabilization of a Pd(IV) tris-alkyl moiety after oxidative addition with MeI. The crucial role of the org...

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Detalles Bibliográficos
Autores principales: Goudy, Violaine, Jaoul, Arnaud, Cordier, Marie, Clavaguéra, Carine, Nocton, Grégory
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5553092/
https://www.ncbi.nlm.nih.gov/pubmed/28741942
http://dx.doi.org/10.1021/jacs.7b05634

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5553092/
https://www.ncbi.nlm.nih.gov/pubmed/28741942
http://dx.doi.org/10.1021/jacs.7b05634

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