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Tuning the Stability of Pd(IV) Intermediates Using a Redox Non-innocent Ligand Combined with an Organolanthanide Fragment
[Image: see text] The unique combination of a divalent organolanthanide fragment, Cp*(2)Yb, with bipyrimidine (bipym) and a palladium bis-alkyl fragment, PdMe(2), allows the rapid formation and stabilization of a Pd(IV) tris-alkyl moiety after oxidative addition with MeI. The crucial role of the org...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5553092/ https://www.ncbi.nlm.nih.gov/pubmed/28741942 http://dx.doi.org/10.1021/jacs.7b05634 |