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The structure of vanadium nitrogenase reveals an unusual bridging ligand
Nitrogenases catalyze the reduction of N(2) gas to ammonium at a complex heterometallic cofactor. Most commonly this is the FeMo cofactor (FeMoco), a [Mo:7Fe:9S:C] cluster whose exact reactivity and substrate binding mode remain unknown. Alternative nitrogenases replace molybdenum with either vanadi...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5563456/ https://www.ncbi.nlm.nih.gov/pubmed/28692069 http://dx.doi.org/10.1038/nchembio.2428 |