Temperature‐Dependence of the Rates of Reaction of Trifluoroacetic Acid with Criegee Intermediates

The rate coefficients for gas‐phase reaction of trifluoroacetic acid (TFA) with two Criegee intermediates, formaldehyde oxide and acetone oxide, decrease with increasing temperature in the range 240–340 K. The rate coefficients k(CH(2)OO + CF(3)COOH)=(3.4±0.3)×10(−10) cm(3) s(−1) and k((CH(3))(2)COO...

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Detalles Bibliográficos
Autores principales: Chhantyal‐Pun, Rabi, McGillen, Max R., Beames, Joseph M., Khan, M. Anwar H., Percival, Carl J., Shallcross, Dudley E., Orr‐Ewing, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5575497/
https://www.ncbi.nlm.nih.gov/pubmed/28614628
http://dx.doi.org/10.1002/anie.201703700

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5575497/
https://www.ncbi.nlm.nih.gov/pubmed/28614628
http://dx.doi.org/10.1002/anie.201703700

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