Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV)

The reaction of [Zr(Tren(DMBS))(Cl)] [Zr1; Tren(DMBS)=N(CH(2)CH(2)NSiMe(2)Bu(t))(3)] with NaPH(2) gave the terminal parent phosphanide complex [Zr(Tren(DMBS))(PH(2))] [Zr2; Zr−P=2.690(2) Å]. Treatment of Zr2 with one equivalent of KCH(2)C(6)H(5) and two equivalents of benzo‐15‐crown‐5 ether (B15C5)...

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Detalles Bibliográficos
Autores principales: Stafford, Hannah, Rookes, Thomas M., Wildman, Elizabeth P., Balázs, Gábor, Wooles, Ashley J., Scheer, Manfred, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5575506/
https://www.ncbi.nlm.nih.gov/pubmed/28489308
http://dx.doi.org/10.1002/anie.201703870

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5575506/
https://www.ncbi.nlm.nih.gov/pubmed/28489308
http://dx.doi.org/10.1002/anie.201703870

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