Cargando…

Terminal Parent Phosphanide and Phosphinidene Complexes of Zirconium(IV)

The reaction of [Zr(Tren(DMBS))(Cl)] [Zr1; Tren(DMBS)=N(CH(2)CH(2)NSiMe(2)Bu(t))(3)] with NaPH(2) gave the terminal parent phosphanide complex [Zr(Tren(DMBS))(PH(2))] [Zr2; Zr−P=2.690(2) Å]. Treatment of Zr2 with one equivalent of KCH(2)C(6)H(5) and two equivalents of benzo‐15‐crown‐5 ether (B15C5)...

Descripción completa

Detalles Bibliográficos
Autores principales:	Stafford, Hannah, Rookes, Thomas M., Wildman, Elizabeth P., Balázs, Gábor, Wooles, Ashley J., Scheer, Manfred, Liddle, Stephen T.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5575506/ https://www.ncbi.nlm.nih.gov/pubmed/28489308 http://dx.doi.org/10.1002/anie.201703870

Ejemplares similares

Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
por: Wildman, Elizabeth P., et al.
Publicado: (2017)

Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
por: Wildman, Elizabeth P., et al.
Publicado: (2016)

Author Correction: Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions
por: Wildman, Elizabeth P., et al.
Publicado: (2023)

Actinide Pnictinidene Chemistry: A Terminal Thorium Parent‐Arsinidene Complex Stabilised by a Super‐Bulky Triamidoamine Ligand
por: Du, Jingzhen, et al.
Publicado: (2022)

Crystalline Diuranium Phosphinidiide and μ‐Phosphido Complexes with Symmetric and Asymmetric UPU Cores
por: Rookes, Thomas M., et al.
Publicado: (2017)

Actinide–Pnictide (An−Pn) Bonds Spanning Non‐Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi)
por: Rookes, Thomas M., et al.
Publicado: (2017)

The “Hidden” Reductive [2+2+1]‐Cycloaddition Chemistry of 2‐Phosphaethynolate Revealed by Reduction of a Th‐OCP Linkage
por: Du, Jingzhen, et al.
Publicado: (2020)

Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex
por: Gardner, Benedict M, et al.
Publicado: (2015)

Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex
por: Gardner, Benedict M., et al.
Publicado: (2015)

Heteroleptic actinocenes: a thorium(iv)–cyclobutadienyl–cyclooctatetraenyl–di-potassium-cyclooctatetraenyl complex
por: Boronski, Josef T., et al.
Publicado: (2020)

Silyl‐Phosphino‐Carbene Complexes of Uranium(IV)
por: Lu, Erli, et al.
Publicado: (2018)

Mesoionic Carbene Complexes of Uranium(IV) and Thorium(IV)
por: Seed, John A., et al.
Publicado: (2022)

Experimental and Computational Studies on a Base‐Free Terminal Uranium Phosphinidene Metallocene
por: Wang, Deqiang, et al.
Publicado: (2020)

Synthesis and Structural Characterization of Phosphanide Gold(III)/Gold(I) Complexes and Their Thallium(III) and Gold(III) Precursors
por: Coconubo-Guio, Laura, et al.
Publicado: (2023)

Cyano(triphenylsilyl)phosphanide as a Building Block for P,C,N Conjugated Molecules
por: Le Corre, Grégoire, et al.
Publicado: (2021)

Comparison of group 4 and thorium M(iv) substituted cyclopentadienyl silanide complexes
por: Réant, Benjamin L. L., et al.
Publicado: (2023)

A Carbene‐Stabilized Boryl‐Phosphinidene
por: Kumar Sarkar, Samir, et al.
Publicado: (2022)

Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer
por: Abbenseth, Josh, et al.
Publicado: (2019)

N‐Heterocyclic Carbene Analogues of Nucleophilic Phosphinidene Transition Metal Complexes
por: Doddi, Adinarayana, et al.
Publicado: (2020)

The Parent Diarsene HAs=AsH as Side‐on Bound Ligand in an Iron Carbonyl Complex
por: Rund, Reinhard, et al.
Publicado: (2019)

Iron‐ and Cobalt‐Catalyzed Synthesis of Carbene Phosphinidenes
por: Pal, Kuntal, et al.
Publicado: (2015)

Tales of the Unexpected: The Case of Zirconium(IV) Complexes with Desferrioxamine
por: Savastano, Matteo, et al.
Publicado: (2019)

Assessing crystal field and magnetic interactions in diuranium-μ-chalcogenide triamidoamine complexes with U(IV)–E–U(IV) cores (E = S, Se, Te): implications for determining the presence or absence of actinide–actinide magnetic exchange
por: Gardner, Benedict M., et al.
Publicado: (2017)

A Very Short Uranium(IV)–Rhodium(I) Bond with Net Double‐Dative Bonding Character
por: Lu, Erli, et al.
Publicado: (2018)

Novel synthetic route for (parent) phosphetanes, phospholanes, phosphinanes and phosphepanes
por: Reichl, Stephan, et al.
Publicado: (2023)

Synthesis of acyl(chloro)phosphines enabled by phosphinidene transfer
por: Szkop, Kevin M., et al.
Publicado: (2019)

Correction: Novel synthetic route for (parent) phosphetanes, phospholanes, phosphinanes and phosphepanes
por: Reichl, Stephan, et al.
Publicado: (2023)

Isoselective Polymerization of rac‐Lactide by Aluminum Complexes of N‐Heterocyclic Carbene‐Phosphinidene Adducts
por: Bhattacharjee, Jayeeta, et al.
Publicado: (2021)

Evidence for ligand- and solvent-induced disproportionation of uranium(IV)
por: Du, Jingzhen, et al.
Publicado: (2021)

Synthesis and Characterization of an f-Block Terminal Parent Imido [U=NH] Complex: A Masked Uranium(IV) Nitride
por: King, David M., et al.
Publicado: (2014)

Thorium-nitrogen multiple bonds provide evidence for pushing-from-below for early actinides
por: Du, Jingzhen, et al.
Publicado: (2019)

Synthesis and Coordination Ability of a Donor‐Stabilised Bis‐Phosphinidene
por: Hadlington, Terrance J., et al.
Publicado: (2020)

Synthesis, Spectral and Antibacterial Studies of Binuclear Titanium(IV) / Zirconium(IV) Complexes of Piperazine Dithiosemicarbazones
por: Pandey, O. P., et al.
Publicado: (2003)

Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes
por: King, David M., et al.
Publicado: (2016)

Synthesis and Characterization of Yttrium Methanediide Silanide Complexes
por: Réant, Benjamin L. L., et al.
Publicado: (2022)

Zirconium(IV) dilanthanum(III) pentasulfide
por: Raw, Adam D., et al.
Publicado: (2011)

Treatment of Silylene–Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon‐Bonded Chalcogens
por: Sinhababu, Soumen, et al.
Publicado: (2019)

Non‐conventional Behavior of a 2,1‐Benzazaphosphole: Heterodiene or Hidden Phosphinidene?
por: Kremláček, Vít, et al.
Publicado: (2021)

Synthesis of phosphiranes via organoiron-catalyzed phosphinidene transfer to electron-deficient olefins
por: Xin, Tiansi, et al.
Publicado: (2022)

Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
por: Chatelain, Lucile, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_kpg2tctgdf819ku5e3i9q9k9h1