Frustrated Lewis Pair Mediated 1,2‐Hydrocarbation of Alkynes

Frustrated Lewis pair (FLP) chemistry enables a rare example of alkyne 1,2‐hydrocarbation with N‐methylacridinium salts as the carbon Lewis acid. This 1,2‐hydrocarbation process does not proceed through a concerted mechanism as in alkyne syn‐hydroboration, or through an intramolecular 1,3‐hydride mi...

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Detalles Bibliográficos
Autores principales: Fasano, Valerio, Curless, Liam D., Radcliffe, James E., Ingleson, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5577509/
https://www.ncbi.nlm.nih.gov/pubmed/28608991
http://dx.doi.org/10.1002/anie.201705100

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5577509/
https://www.ncbi.nlm.nih.gov/pubmed/28608991
http://dx.doi.org/10.1002/anie.201705100

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